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- W2426795413 abstract "Organic molecular cage (CC3-R) with intrinsically porous skeleton is used as a support for immobilizing Rh nanoparticles (NPs) in an ultrasmall size of ∼1.1 nm for the first time. The CC3-R with the unique characteristic of high solubility can be utilized to homogenize the heterogeneous catalyst in solution. The obtained homogenized heterogeneous catalyst Rh/CC3-R-homo exhibits significantly enhanced catalytic performance toward various liquid-phase catalytic reactions, as compared with the heterogeneous counterpart Rh/CC3-R-hetero. Moreover, Rh/CC3-R-homo shows excellent durability and recyclability. The advantage of combining homogeneous and heterogeneous catalysts is likely to be beneficial for many applications." @default.
- W2426795413 created "2016-06-24" @default.
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- W2426795413 date "2015-06-02" @default.
- W2426795413 modified "2023-10-03" @default.
- W2426795413 title "Toward Homogenization of Heterogeneous Metal Nanoparticle Catalysts with Enhanced Catalytic Performance: Soluble Porous Organic Cage as a Stabilizer and Homogenizer" @default.
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- W2426795413 doi "https://doi.org/10.1021/jacs.5b04029" @default.
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