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- W2427360023 abstract "Synthesis of a metal–organic framework (MOF)-supported olefin metathesis catalyst has been accomplished for the first time following a new, convergent approach where an aldehyde-functionalized derivative of Hoveyda’s recently reported ruthenium catecholate olefin metathesis catalyst is condensed with an amine-functionalized IRMOF-74-III. The resulting material, denoted MOF-Ru, has well-defined, catalytically active ruthenium centers confined within channels having a ca. 20 A diameter. MOF-Ru is a recyclable, single-site catalyst for self-cross-metathesis and ring-closing metathesis of terminal olefins. Comparison of this heterogeneous catalyst with a homogeneous analogue shows different responses to substrate size and shape suggestive of confinement effects. The MOF-Ru catalyst also displays greater resistance to double-bond migration that can be attributed to greater catalyst stability. For the preparation of well-defined, single-site heterogeneous catalysts where catalyst purity is essential, the conver..." @default.
- W2427360023 created "2016-06-24" @default.
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- W2427360023 date "2016-06-15" @default.
- W2427360023 modified "2023-09-24" @default.
- W2427360023 title "Convergent Synthesis of a Metal–Organic Framework Supported Olefin Metathesis Catalyst" @default.
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- W2427360023 doi "https://doi.org/10.1021/acs.organomet.6b00365" @default.
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