Matches in SemOpenAlex for { <https://semopenalex.org/work/W2429643697> ?p ?o ?g. }
- W2429643697 endingPage "14565" @default.
- W2429643697 startingPage "14562" @default.
- W2429643697 abstract "The reactivity of peroxide dianion O2(2-) has been scarcely explored in organic media due to the lack of soluble sources of this reduced oxygen species. We now report the finding that the encapsulated peroxide cryptate, [O2⊂mBDCA-5t-H6](2-) (1), reacts with carbon monoxide in organic solvents at 40 °C to cleanly form an encapsulated carbonate. Characterization of the resulting hexacarboxamide carbonate cryptate by single crystal X-ray diffraction reveals that carbonate dianion forms nine complementary hydrogen bonds with the hexacarboxamide cryptand, [CO3⊂mBDCA-5t-H6](2-) (2), a conclusion that is supported by spectroscopic data. Labeling studies and (17)O solid-state NMR data confirm that two-thirds of the oxygen atoms in the encapsulated carbonate derive from peroxide dianion, while the carbon is derived from CO. Further evidence for the formation of a carbonate cryptate was obtained by three methods of independent synthesis: treatment of (i) free cryptand with K2CO3; (ii) monodeprotonated cryptand with PPN[HCO3]; and (iii) free cryptand with TBA[OH] and atmospheric CO2. This work demonstrates CO oxidation mediated by a hydrogen-bonding anion receptor, constituting an alternative to transition-metal catalysis." @default.
- W2429643697 created "2016-06-24" @default.
- W2429643697 creator A5016347535 @default.
- W2429643697 creator A5030912317 @default.
- W2429643697 creator A5050979141 @default.
- W2429643697 creator A5056442308 @default.
- W2429643697 creator A5063169585 @default.
- W2429643697 creator A5085656195 @default.
- W2429643697 date "2015-11-12" @default.
- W2429643697 modified "2023-09-30" @default.
- W2429643697 title "Anion-Receptor Mediated Oxidation of Carbon Monoxide to Carbonate by Peroxide Dianion" @default.
- W2429643697 cites W1982643872 @default.
- W2429643697 cites W1988195234 @default.
- W2429643697 cites W1991003106 @default.
- W2429643697 cites W1995824822 @default.
- W2429643697 cites W1995846141 @default.
- W2429643697 cites W1998101840 @default.
- W2429643697 cites W2000805999 @default.
- W2429643697 cites W2001591025 @default.
- W2429643697 cites W2007485303 @default.
- W2429643697 cites W2025850738 @default.
- W2429643697 cites W2034248489 @default.
- W2429643697 cites W2034657794 @default.
- W2429643697 cites W2039481223 @default.
- W2429643697 cites W2045928837 @default.
- W2429643697 cites W2046842663 @default.
- W2429643697 cites W2048482262 @default.
- W2429643697 cites W2051985544 @default.
- W2429643697 cites W2055528556 @default.
- W2429643697 cites W2056952624 @default.
- W2429643697 cites W2058368889 @default.
- W2429643697 cites W2060885597 @default.
- W2429643697 cites W2066125417 @default.
- W2429643697 cites W2066743074 @default.
- W2429643697 cites W2067694274 @default.
- W2429643697 cites W2080383031 @default.
- W2429643697 cites W2080545066 @default.
- W2429643697 cites W2081292041 @default.
- W2429643697 cites W2088264696 @default.
- W2429643697 cites W2089959805 @default.
- W2429643697 cites W2099476283 @default.
- W2429643697 cites W2112959450 @default.
- W2429643697 cites W2122424298 @default.
- W2429643697 cites W2124845074 @default.
- W2429643697 cites W2126688530 @default.
- W2429643697 cites W2129213730 @default.
- W2429643697 cites W2134569344 @default.
- W2429643697 cites W2170939200 @default.
- W2429643697 cites W2171238543 @default.
- W2429643697 cites W2313247439 @default.
- W2429643697 cites W2318865563 @default.
- W2429643697 cites W2319030935 @default.
- W2429643697 cites W2332318867 @default.
- W2429643697 cites W2334525018 @default.
- W2429643697 cites W288120575 @default.
- W2429643697 cites W2952262467 @default.
- W2429643697 doi "https://doi.org/10.1021/jacs.5b08495" @default.
- W2429643697 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26465825" @default.
- W2429643697 hasPublicationYear "2015" @default.
- W2429643697 type Work @default.
- W2429643697 sameAs 2429643697 @default.
- W2429643697 citedByCount "25" @default.
- W2429643697 countsByYear W24296436972016 @default.
- W2429643697 countsByYear W24296436972017 @default.
- W2429643697 countsByYear W24296436972018 @default.
- W2429643697 countsByYear W24296436972019 @default.
- W2429643697 countsByYear W24296436972020 @default.
- W2429643697 countsByYear W24296436972021 @default.
- W2429643697 countsByYear W24296436972022 @default.
- W2429643697 crossrefType "journal-article" @default.
- W2429643697 hasAuthorship W2429643697A5016347535 @default.
- W2429643697 hasAuthorship W2429643697A5030912317 @default.
- W2429643697 hasAuthorship W2429643697A5050979141 @default.
- W2429643697 hasAuthorship W2429643697A5056442308 @default.
- W2429643697 hasAuthorship W2429643697A5063169585 @default.
- W2429643697 hasAuthorship W2429643697A5085656195 @default.
- W2429643697 hasBestOaLocation W24296436971 @default.
- W2429643697 hasConcept C114595235 @default.
- W2429643697 hasConcept C142724271 @default.
- W2429643697 hasConcept C145148216 @default.
- W2429643697 hasConcept C161790260 @default.
- W2429643697 hasConcept C178790620 @default.
- W2429643697 hasConcept C179104552 @default.
- W2429643697 hasConcept C185592680 @default.
- W2429643697 hasConcept C204787440 @default.
- W2429643697 hasConcept C2776910235 @default.
- W2429643697 hasConcept C2780659211 @default.
- W2429643697 hasConcept C2781048764 @default.
- W2429643697 hasConcept C2910723988 @default.
- W2429643697 hasConcept C512735826 @default.
- W2429643697 hasConcept C533411734 @default.
- W2429643697 hasConcept C71924100 @default.
- W2429643697 hasConceptScore W2429643697C114595235 @default.
- W2429643697 hasConceptScore W2429643697C142724271 @default.
- W2429643697 hasConceptScore W2429643697C145148216 @default.
- W2429643697 hasConceptScore W2429643697C161790260 @default.
- W2429643697 hasConceptScore W2429643697C178790620 @default.
- W2429643697 hasConceptScore W2429643697C179104552 @default.