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• W2431058809 abstract "Abstract Recent studies have identified carbonaceous material in serpentinite bodies, but whether these deposits have a biologic or abiotic origin remains uncertain. In this work, thermodynamic calculations were performed to examine the potential for abiotic condensed carbonaceous material to be produced from serpentinization-derived fluids under hydrothermal conditions. Calculation of reaction pathways during serpentinization of olivine showed that fluid compositions should equilibrate with condensed carbonaceous material, which controls the H 2 and CO 2 activities. Fluids from laboratory serpentinization experiments and from the Lost City and the Rainbow hydrothermal field are shown to be consistent with this model. The predictions indicate that carbonaceous material should be the dominant carbon product of CO 2 reduction in these hydrothermal settings, which would have significant implications for a number of processes, including the deep Earth carbon cycle by creating a pool of relatively immobile reduced carbon, the extent of H 2 production in ultrabasic environments, and mechanisms leading to abiotic reduced carbon compounds." @default.
• W2431058809 created "2016-06-24" @default.
• W2431058809 creator A5061083313 @default.
• W2431058809 creator A5071942045 @default.
• W2431058809 creator A5086168773 @default.
• W2431058809 date "2016-09-01" @default.
• W2431058809 modified "2023-10-01" @default.
• W2431058809 title "Thermodynamic constraints on the formation of condensed carbon from serpentinization fluids" @default.
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• W2431058809 doi "https://doi.org/10.1016/j.gca.2016.06.006" @default.
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