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- W2434630198 abstract "In the presence of a carbodiimine, i.e. DCC, a series of organoimido derivatives of polyoxometalates have been synthesized via the reaction of [alpha-Mo8O26]4- with aromatic amines and its hydrochloride salt. Elemental analysis, IR, 1H-NMR and UV-Vis spectra were used to characterize those hybrids, in particular their UV-Vis spectra have been studied. The results show that typical metal-ligand charge transfer (MLCT) transitions occur in the organic-inorganic hybrid molecules. There is a good linear relationship between the shift of UV-Vis absorptions (delta lamda max) and conjugation effect of the p-substituted group (sigmaR)." @default.
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- W2434630198 date "2005-06-01" @default.
- W2434630198 modified "2023-09-26" @default.
- W2434630198 title "[The UV-Vis spectra and substituent effect of organoimido derivatives of polyoxometalates]." @default.
- W2434630198 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16201373" @default.
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