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• W2434857568 endingPage "3397" @default.
• W2434857568 startingPage "3394" @default.
• W2434857568 abstract "Readily available NHC-arylboranes (NHC-BH2Ar) are converted in high yield to stable NHC-difluoro(aryl)boranes (NHC-BF2Ar) by treatment with 2 equiv of 1-chloromethyl-4-fluoro-1,4-diazonia-bicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor). In turn, the NHC-difluoro(aryl)boranes participate directly in Suzuki reactions under conditions previously used for anionic trifluoroborate salts. Accordingly, NHC-difluoroboranes are a new class of stable precursors for Suzuki reactions." @default.
• W2434857568 created "2016-06-24" @default.
• W2434857568 creator A5054268082 @default.
• W2434857568 creator A5058483916 @default.
• W2434857568 date "2015-07-06" @default.
• W2434857568 modified "2023-10-18" @default.
• W2434857568 title "Synthesis and Suzuki Reactions of N-Heterocyclic Carbene Difluoro(aryl)-boranes" @default.
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• W2434857568 doi "https://doi.org/10.1021/acs.orglett.5b01101" @default.
• W2434857568 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26147155" @default.
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