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- W2435331308 endingPage "5794" @default.
- W2435331308 startingPage "5789" @default.
- W2435331308 abstract "An efficient Suzuki-Miyaura cross-coupling reaction of perfluorinated arenes with aryl boronate esters using NHC nickel complexes as catalysts is described. The efficiencies of different boronate esters (p-tolyl-Beg, p-tolyl-Bneop, p-tolyl-Bpin, p-tolyl-Bcat) and the corresponding boronic acid (p-tolyl-B(OH)2) in this type of cross-coupling reaction were evaluated (eg, ethyleneglycolato; neop, neopentylglycolato; pin, pinacolato; cat, catecholato). Aryl-Beg was shown to be the most reactive boronate ester among those studied. The use of CsF as an additive is essential for an efficient reaction of hexafluorobenzene with aryl neopentylglycolboronates." @default.
- W2435331308 created "2016-06-24" @default.
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- W2435331308 date "2016-06-15" @default.
- W2435331308 modified "2023-10-02" @default.
- W2435331308 title "NHC Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions of Aryl Boronate Esters with Perfluorobenzenes" @default.
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- W2435331308 doi "https://doi.org/10.1021/acs.joc.6b01041" @default.
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