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- W2435783975 abstract "Spiniferin-1, a rare planar chiral natural product with a 1,6-methano[10]annulene skeleton, has been synthesized via a novel polyfluoroalkanosulfonyl fluoride induced cascade carbocation rearrangement reaction. Natural spiniferin-1 was established as a racemic mixture by comparing its specific rotation with those of our synthesized <i>S<sub>p</sub> </i>-(+)-spiniferin-1 and its <i>R<sub>p</sub> </i>-(–)-enantiomer." @default.
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- W2435783975 date "2013-01-31" @default.
- W2435783975 modified "2023-09-27" @default.
- W2435783975 title "Total Synthesis and Establishment of the Stereochemistry of Spiniferin-1, a Rare Planar Chiral Marine Natural Product with a 1,6-Methano[10]annulene Skeleton" @default.
- W2435783975 doi "https://doi.org/10.1055/s-0032-1318105" @default.
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