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- W2438818400 abstract "The intermediate radicals produced in the gas-phase pyrolysis of one of the main building blocks of lignin - p-coumaryl alcohol (p-CMA) - were investigated using the low temperature matrix isolation technique interfaced with electron paramagnetic resonance spectroscopy (LTMI-EPR). An anisotropic EPR spectrum characterized by a high g-value (>2.0080) and a relatively low saturation coefficient (∼1.40) throughout the high pyrolytic temperature region (700 to 1000 °C) was observed. Theoretical calculations revealed plausible decomposition pathways for p-CMA comprising highly delocalized aromatic radicals. The results provide evidence for a dominant role of oxygen-centered radicals during the pyrolysis of p-CMA." @default.
- W2438818400 created "2016-06-24" @default.
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- W2438818400 date "2016-01-01" @default.
- W2438818400 modified "2023-10-14" @default.
- W2438818400 title "Radicals from the gas-phase pyrolysis of a lignin model compound: p-coumaryl alcohol" @default.
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- W2438818400 doi "https://doi.org/10.1039/c6ra11372a" @default.
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