Matches in SemOpenAlex for { <https://semopenalex.org/work/W2439044633> ?p ?o ?g. }
- W2439044633 endingPage "14488" @default.
- W2439044633 startingPage "14484" @default.
- W2439044633 abstract "Directly utilizing a chemical feedstock to construct valuable compounds is an attractive prospect in organic synthesis. In particular, the combination of C(sp(3) )-H activation and oxidative carbonylation involving alkanes and CO gas is a promising and efficient method to synthesize carbonyl derivatives. However, due to the high C-H bond dissociation energy and low polarity of unactivated alkanes, the carbonylation of unactivated C(sp(3) )-H bonds still remains a great challenge. In this work, we introduce a palladium-catalyzed radical oxidative alkoxycarbonylation of alkanes to prepare numerous alkyl carboxylates. Various alkanes and alcohols were compatible, generating the desired products in up to 94 % yield. Remarkably, ethane, a constituent of natural gas, could be employed as a substrate under the standard reaction conditions. Preliminary mechanistic studies revealed a probable palladium-catalyzed radical process." @default.
- W2439044633 created "2016-06-24" @default.
- W2439044633 creator A5009669197 @default.
- W2439044633 creator A5026670324 @default.
- W2439044633 creator A5029531444 @default.
- W2439044633 creator A5059624153 @default.
- W2439044633 creator A5061246868 @default.
- W2439044633 creator A5087742087 @default.
- W2439044633 date "2016-08-19" @default.
- W2439044633 modified "2023-10-17" @default.
- W2439044633 title "Oxidative Alkane C−H Alkoxycarbonylation" @default.
- W2439044633 cites W1964610021 @default.
- W2439044633 cites W1964905538 @default.
- W2439044633 cites W1965119585 @default.
- W2439044633 cites W1971720956 @default.
- W2439044633 cites W1976801308 @default.
- W2439044633 cites W1977066177 @default.
- W2439044633 cites W1988528758 @default.
- W2439044633 cites W1995417874 @default.
- W2439044633 cites W1996809799 @default.
- W2439044633 cites W1998638230 @default.
- W2439044633 cites W2001449419 @default.
- W2439044633 cites W2004292643 @default.
- W2439044633 cites W2006108545 @default.
- W2439044633 cites W2007721898 @default.
- W2439044633 cites W2008263542 @default.
- W2439044633 cites W2011722581 @default.
- W2439044633 cites W2019406135 @default.
- W2439044633 cites W2031424416 @default.
- W2439044633 cites W2033614178 @default.
- W2439044633 cites W2044178974 @default.
- W2439044633 cites W2046443922 @default.
- W2439044633 cites W2056637308 @default.
- W2439044633 cites W2060296131 @default.
- W2439044633 cites W2061142370 @default.
- W2439044633 cites W2061570820 @default.
- W2439044633 cites W2066309940 @default.
- W2439044633 cites W2067341932 @default.
- W2439044633 cites W2069282965 @default.
- W2439044633 cites W2079982106 @default.
- W2439044633 cites W2081654257 @default.
- W2439044633 cites W2083044747 @default.
- W2439044633 cites W2083175411 @default.
- W2439044633 cites W2084235449 @default.
- W2439044633 cites W2088019388 @default.
- W2439044633 cites W2089909277 @default.
- W2439044633 cites W2097466483 @default.
- W2439044633 cites W2099004477 @default.
- W2439044633 cites W2099584862 @default.
- W2439044633 cites W2103172054 @default.
- W2439044633 cites W2112196245 @default.
- W2439044633 cites W2119459897 @default.
- W2439044633 cites W2122112579 @default.
- W2439044633 cites W2140617505 @default.
- W2439044633 cites W2151882027 @default.
- W2439044633 cites W2165614767 @default.
- W2439044633 cites W2313299612 @default.
- W2439044633 cites W2325816675 @default.
- W2439044633 cites W2332015190 @default.
- W2439044633 cites W2332399537 @default.
- W2439044633 cites W2332403486 @default.
- W2439044633 cites W2411318579 @default.
- W2439044633 cites W2950418248 @default.
- W2439044633 cites W2950678427 @default.
- W2439044633 cites W2951266793 @default.
- W2439044633 cites W2951403859 @default.
- W2439044633 cites W2951751905 @default.
- W2439044633 cites W340894558 @default.
- W2439044633 cites W4210958078 @default.
- W2439044633 cites W4234050482 @default.
- W2439044633 cites W4240532892 @default.
- W2439044633 cites W4246152400 @default.
- W2439044633 cites W4247712929 @default.
- W2439044633 cites W4252794137 @default.
- W2439044633 doi "https://doi.org/10.1002/chem.201602791" @default.
- W2439044633 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27308821" @default.
- W2439044633 hasPublicationYear "2016" @default.
- W2439044633 type Work @default.
- W2439044633 sameAs 2439044633 @default.
- W2439044633 citedByCount "27" @default.
- W2439044633 countsByYear W24390446332016 @default.
- W2439044633 countsByYear W24390446332017 @default.
- W2439044633 countsByYear W24390446332018 @default.
- W2439044633 countsByYear W24390446332019 @default.
- W2439044633 countsByYear W24390446332020 @default.
- W2439044633 countsByYear W24390446332021 @default.
- W2439044633 countsByYear W24390446332022 @default.
- W2439044633 countsByYear W24390446332023 @default.
- W2439044633 crossrefType "journal-article" @default.
- W2439044633 hasAuthorship W2439044633A5009669197 @default.
- W2439044633 hasAuthorship W2439044633A5026670324 @default.
- W2439044633 hasAuthorship W2439044633A5029531444 @default.
- W2439044633 hasAuthorship W2439044633A5059624153 @default.
- W2439044633 hasAuthorship W2439044633A5061246868 @default.
- W2439044633 hasAuthorship W2439044633A5087742087 @default.
- W2439044633 hasConcept C102931765 @default.
- W2439044633 hasConcept C134121241 @default.
- W2439044633 hasConcept C161790260 @default.