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- W2440891915 abstract "Two iron(II) complexes with tetraazadentate ligands have been synthesised, characterised and evaluated as water oxidation catalysts. The two ligands, N,N′-diisopropyl-N,N′-bis(2-pyridylmethyl)-1,2-diaminoethane (1), and N-methyl-N-(2-pyridinylmethyl)-2,2′-bipyridine-6-methanamine (2), both give iron(II) complexes (1Fe and 2Fe, respectively) with an octahedral coordination geometry with two labile triflate ligands in a cis configuration in the crystal structures. When treated with cerium(IV) as a chemical oxidant in aqueous solution at room temperature the complexes form semi-stable FeIV(O) species that can be detected in the UV/Visible region. Both 1Fe and 2Fe can act as catalysts for water oxidation when treated with a large excess of oxidant, but 1Fe is a better catalyst than 2Fe. Possible geometrical factors behind this difference in reactivity are discussed and compared with literature data." @default.
- W2440891915 created "2016-06-24" @default.
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- W2440891915 date "2016-06-15" @default.
- W2440891915 modified "2023-09-27" @default.
- W2440891915 title "Mononuclear Iron Complexes with Tetraazadentate Ligands as Water Oxidation Catalysts" @default.
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- W2440891915 doi "https://doi.org/10.1002/ejic.201600165" @default.
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