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- W2441027448 abstract "The enantioselective preparation of the two diastereoisomeric forms of 2,15-dihydroxycalamele‘ne and 2-methoxycalamenene is here described. The (7 S,10 R) and (7 R,10 R) isomers of these natural products were synthesized starting from (5 R,8 S)-methyl-4-hydroxy-8-isopropyl-5-methyl-5,6,7,8-tetrahydronaphthalene-2-carboxylate and (5 R,8 R)-methyl-4-hydroxy-8-isopropyl-5-methyl-5,6,7,8-tetrahydronaphthalene-2-carboxylate, respectively, in turn preparable from (-)-menthone and (+)-isomenthone. The NMR analysis of the obtained sesquiterpenes allow assigning (7 R,10 S) absolute configuration to the natural occurring 2,15-dihydroxycalamelene." @default.
- W2441027448 created "2016-06-24" @default.
- W2441027448 creator A5079657887 @default.
- W2441027448 date "2015-08-01" @default.
- W2441027448 modified "2023-09-25" @default.
- W2441027448 title "Stereoselective Synthesis of 2,15-Dihydroxycalamenene and 2-Methoxycalamenene. Determination of the Configuration of Natural 2,15-Dihydroxycalamenene" @default.
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- W2441027448 doi "https://doi.org/10.1177/1934578x1501000803" @default.
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