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- W244176211 abstract "Corrosion rates determined at 1 month in 150/degree/C brine increased with magnesium concentration. The structure of the corrosion product, as determined by x-ray diffraction, depended upon the magnesium concentration. In brines with less than 10,000 ppM magnesium, the primary corrosion product had a spinel structure characteristic of magnetite or magnesioferrite. In brines containing magnesium concentrations greater than 20,000 ppM, the primary corrosion product had the amakinite structure characteristic of a complex iron-magnesium hydroxide. The high corrosion rates observed in brines containing high magnesium concentrations suggest that the corrosion products having the amakinite structure is less protective than corrosion products having the spinel structure. Corrosion rates in high-magnesium (inclusion) brine determined over a 6-month test duration were essentially constant. Hydrogen permeation rates observed in exposing mild steel to high-Mg/sup 2/plus// brine at 150/degree/C could be potentially damaging to a mild steel waste package container. The rate of hydrogen permeation was proportional to the brine flow rate in the autoclave. Thiourea additions to the brine increased the hydrogen permeation rate; sulfate and bromide ion additions did not. The maximum gaseous hydrogen pressure attainable is not known (based on 3Fe /plus/ 4H/sub 2/O /plus/ Fe(sub 3)O /plus/ 4H/sub 2/, would be /approximately/900 atmospheres),more » and the dependence of permeation rate on temperature is not known. 8 refs., 13 figs., 3 tabs.« less" @default.
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- W244176211 date "1988-03-01" @default.
- W244176211 modified "2023-09-27" @default.
- W244176211 title "Corrosion and hydrogen permeation of A216 Grade WCA steel in hydrothermal magnesium-containing brines" @default.
- W244176211 hasPublicationYear "1988" @default.
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