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- W2442433314 abstract "Spontaneous electroless deposition of ultrafine metal nanoparticles (NPs) supported on covalent organic frameworks (COFs) for catalytic organic transformation is rarely reported. Herein, poly(phenylene butadiynylene)s (PPBs), a easily prepared two-dimensional (2D) covalent organic frameworks (COFs) consisting of sp- and sp2-hybridized carbon atoms, can be applied as the reducing agent and substrate for spontaneous electroless deposition of sub-3 nm ultrafine palladium nanoparticles owing to its low reduction potential and highly conjugated electronic structure. The as-formed Pd/PPBs heterogeneous catalyst exhibits excellent recyclability and superior catalytic activity towards hydroxycarbonylation of aryl iodides in the presence of carbon monoxide and water." @default.
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- W2442433314 date "2016-06-01" @default.
- W2442433314 modified "2023-09-24" @default.
- W2442433314 title "Spontaneous Electroless Deposition of Ultrafine Pd Nanoparticles on Poly(phenylene butadiynylene)s for the Hydroxycarbonylation of Aryl Iodides" @default.
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- W2442433314 doi "https://doi.org/10.1002/slct.201600302" @default.
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