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• W2443240717 endingPage "5456" @default.
• W2443240717 startingPage "5444" @default.
• W2443240717 abstract "Novel and selective synthetic approaches toward indole derivatives via copper-catalyzed one-pot multicomponent cascade reactions of 1-bromo-2-(2,2-dibromovinyl)benzenes with aldehydes and aqueous ammonia are presented. Intriguingly, the concentration of ammonia, the molar ratio of reagents, and the structural features of the aldehyde substrate serve as key factors in controlling the selective formation of 3-cyano-1H-indoles, 9H-pyrimido[4,5-b]indoles, or 9H-pyrido[2,3-b]indoles. Compared with literature procedures, the synthetic approaches reported herein have advantages such as readily available starting materials, mild reaction conditions, and divergent reaction patterns toward different products with easily tunable selectivity." @default.
• W2443240717 created "2016-06-24" @default.
• W2443240717 creator A5010299185 @default.
• W2443240717 creator A5029695887 @default.
• W2443240717 creator A5043966211 @default.
• W2443240717 creator A5045032962 @default.
• W2443240717 creator A5062525171 @default.
• W2443240717 date "2015-05-18" @default.
• W2443240717 modified "2023-10-13" @default.
• W2443240717 title "Selective Access to 3-Cyano-1<i>H</i>-indoles, 9<i>H</i>-Pyrimido[4,5-<i>b</i>]indoles, or 9<i>H</i>-Pyrido[2,3-<i>b</i>]indoles through Copper-Catalyzed One-Pot Multicomponent Cascade Reactions" @default.
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