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- W2443283760 abstract "Nowadays, the exploration of highly active and cost-effective bifunctional catalysts for oxygen electrode reactions is crucial for various energy conversion applications. Herein, to obtain a highly effective Co-N/C non-precious metal bifunctional catalyst, 3,5-diamino-1,2,4-triazole (Hdatrz) was used for the first time as a Nitrogen precursor. Different Co-Hdatrz complex weight percentages and thermal treatment temperatures had resulted in varying catalyst performance. Among the resulting catalysts, due to the highest active N content, the smallest charge transfer resistance and the synergy of CoO with carbon black, the Co-N30%/C-600 catalyst (the Co-Hdatrz complex weight percentage was 30% and the thermal treatment temperature was 600 °C) demonstrated the highest catalytic activity towards oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in alkaline medium, which was superior to Pt/C. Additionally, the Co-N30%/C-600 catalyst also showed excellent methanol tolerance and ORR and OER stabilities compared to Pt/C. Thus, the Co-N30%/C-600 catalyst may serve as a promising bifunctional electrocatalyst in fuel cells, metal-air batteries and water splitting cells." @default.
- W2443283760 created "2016-06-24" @default.
- W2443283760 creator A5061074781 @default.
- W2443283760 creator A5076785484 @default.
- W2443283760 date "2016-08-01" @default.
- W2443283760 modified "2023-09-24" @default.
- W2443283760 title "3,5-Diamino-1,2,4-triazole as a Nitrogen precursor to synthesize highly efficient Co-N/C non-precious metal bifunctional catalyst for oxygen reduction reaction and oxygen evolution reaction" @default.
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- W2443283760 doi "https://doi.org/10.1016/j.ijhydene.2016.05.269" @default.
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