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- W2460620788 abstract "The ferrocene/ferrocenium (Fc0/+) redox couple is regarded as a kinetically facile process under voltammetric conditions. It also possesses a nearly “solvent independent” formal potential, and for this reason is commonly used as a “reference” redox system for electrochemical studies in nonaqueous electrolyte media. Fc0/+ has also been adopted as a “model system” in ionic liquid (IL) media, although conflicting reports on the mass-transport and kinetics have brought its “ideality” into question. In this study, the mass-transport and heterogeneous electron-transfer kinetics associated with the Fc0/+ process at a platinum electrode are reported in 14 ILs with dynamic viscosities (η) ranging from 20 to 620 cP. The diffusivity of Fc (DFc) was calculated in each of the ILs using convolution voltammetry and was found to be inversely proportional to the viscosity of the medium, as per the Stokes–Einstein relation (i.e., D ∝ 1/η). The heterogeneous electron-transfer rate constant (k0) associated with the Fc0/+ pro..." @default.
- W2460620788 created "2016-07-22" @default.
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- W2460620788 date "2016-07-20" @default.
- W2460620788 modified "2023-09-29" @default.
- W2460620788 title "Mass-Transport and Heterogeneous Electron-Transfer Kinetics Associated with the Ferrocene/Ferrocenium Process in Ionic Liquids" @default.
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- W2460620788 doi "https://doi.org/10.1021/acs.jpcc.6b05545" @default.
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