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- W2460835503 abstract "A mixture of [(η-C5H5)Ti(μ3-Se)]7 (1) and [(η-C5H5)Ti]5(μ3-Se)6 (2) was formed on reduction of [(η-C5H5)Ti]4(μ2-Se)3(μ3-Se)3 with Bun3SnH. A structure with opposed capped octahedra of Ti and Se atoms is proposed for [(η-C5H5)Ti(μ3-Se)]7 (1) on the basis of spectroscopic data. Oxidation of (η-C5H5)TiCl2·2thf with H2Se in the presence of triethylamine gave [(η-C5H5)Ti]5(μ3-Se)6 (2), which has a trigonal bipyramidal arrangement of Ti atoms (average Tiax−Tieq 3.215(2) Å, average Tieq−Tieq 3.374(3) Å) and is paramagnetic with one unpaired electron." @default.
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- W2460835503 date "1996-01-23" @default.
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- W2460835503 title "Organometallic Selenides: Preparation of [(η-C5H5)Ti(μ3-Se)]7 and [(η-C5H5)Ti]5(μ3-Se)6 by Reduction of [(η-C5H5)Ti]4(μ2-Se)3(μ3-Se)3 with Bun3SnH and Preparation of [(η-C5H5)Ti]5(μ3-Se)6 by Oxidation of (η-C5H5)TiCl2 with H2Se" @default.
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- W2460835503 doi "https://doi.org/10.1021/om950540i" @default.
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