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- W2460977218 abstract "Abstract We report a new strategy for the synthesis of phenols from acyclic unsaturated ketones in one pot. The reaction proceeds by palladium‐catalyzed carbopalladation of an alkene with the enol form of the tethered ketone, generating a substituted cyclohexanone. Upon introduction of a terminal oxidant a palladium‐catalyzed oxidation ensues to give the desired phenol. This approach allows the programming of phenol substituents on the acyclic substrate and therefore circumvents the limitations inherent in traditional syntheses of phenols." @default.
- W2460977218 created "2016-07-22" @default.
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- W2460977218 date "2016-07-13" @default.
- W2460977218 modified "2023-10-14" @default.
- W2460977218 title "A New Route to Phenols: Palladium-Catalyzed Cyclization and Oxidation of γ,δ-Unsaturated Ketones" @default.
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- W2460977218 doi "https://doi.org/10.1002/cctc.201600447" @default.
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