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- W2461085004 abstract "Abstract Different PtPd nanostructured catalysts modified with bismuth have been synthesized on a carbon support. Their activity towards the glycerol electrooxidation reaction has been compared in alkaline medium, and modification with about 10 at % bismuth led to an increase in activity compared with pure metals. Pt 9 Bi 1 /C is the most active catalyst for this reaction, with an oxidation onset potential as low as 0.3 V versus RHE. The hydrogen production in a direct electrolysis cell was evaluated. The Pt 9 Bi 1 /C anode gave a hydrogen production rate of approximately 0.11 and 0.23 Nm 3 h −1 m −2 with an electrical energy consumption of 1.3 or 1.65 kWh (Nm 3 ) −1 at 0.55 or 0.7 V, respectively. Compared with traditional water electrolysis, this is an energy saving of between 66 and 57 %. It was also shown by using in situ FTIR spectroscopy that the modification of platinum with bismuth avoids (or at least drastically reduces) C−C bond breakage, which thus increases selectivity towards value‐added C3 compounds. At low potentials, glyceraldehyde is the main reaction product and at higher potentials, glyceraldehyde and dihydroxyacetone act as reaction intermediates to the formation of carboxylates." @default.
- W2461085004 created "2016-07-22" @default.
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- W2461085004 date "2016-08-02" @default.
- W2461085004 modified "2023-10-18" @default.
- W2461085004 title "Development of Bismuth-Modified PtPd Nanocatalysts for the Electrochemical Reforming of Polyols into Hydrogen and Value-Added Chemicals" @default.
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- W2461085004 doi "https://doi.org/10.1002/celc.201600147" @default.
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