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- W2462428708 abstract "Work on the microstructure of the ring-opened polymers of norbornene, ten of its alkyl derivatives, and some other bicycloalkenes is reviewed. The cis double bond content ranges from 0% (with RuCl3) to 100% (with ReCl5); the cis/trans double bond distribution ranges from statistical to blocky; the monomers without a plane of symmetry give polymers with a range of head-tail bias, from random orientation to total bias; and the ring dyad tacticity may range from atactic to fully tactic in the sense that cis and trans double bonds are associated with r and m dyads respectively. The results are discussed in terms of propagating metal carbene complexes which may or may not have a chiral reaction site and in which the stereochemistry of the previously incorporated unit, attached to the carbene ligand, may influence the next propagation step." @default.
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- W2462428708 date "1985-08-16" @default.
- W2462428708 modified "2023-10-17" @default.
- W2462428708 title "Mechanism of Ring-Opening Polymerization of Bicycloalkenes by Metathesis Catalysts" @default.
- W2462428708 doi "https://doi.org/10.1021/bk-1985-0286.ch021" @default.
- W2462428708 hasPublicationYear "1985" @default.
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