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- W2462441730 abstract "The kinetics of autocatalytic hydrolysis of crude palm oil was studied at moisture below solubility using the isopiestic method, in which the oil was exposed to a volume of sulphuric acid at a certain concentration in a closed system and stored at 55 o C. Different humidities were created by using different concentrations of sulphuric acid, thereby effecting different activities of water in the oil. The reaction rate constants of crude palm oil with different initial free fatty acid contents and initial moisture contents stored under the constant humidities created were determined and studied. The oxidation of the oil samples under these different constant humidities was also studied. Autocatalytic hydrolysis of crude palm oil, or similar glyceridic oil, of a low free fatty acid content, and under constant water activity, follows a zero-order reaction. The rate of reaction is a function of the initial free fatty acid content. The reaction rate constant is a direct function of the initial free fatty acid content and water activity or moisture content. Water activity of >0.50 is desirable for a lower rate of autoxidation of the oil in storage." @default.
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- W2462441730 date "2006-01-31" @default.
- W2462441730 modified "2023-09-26" @default.
- W2462441730 title "Autocatalytic hydrolysis and autoxidation of crude palm oil under various constant humidities" @default.
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