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- W2462677943 abstract "Metallic glasses (MGs) are a relatively new class of materials discovered in 1960and lauded for its high strengths and superior elastic properties. Three major obstaclesprevent their widespread use as engineering materials for nanotechnology andindustry: 1) their lack of plasticity mechanisms for deformation beyond the elasticlimit, 2) their disordered atomic structure, which prevents effective study of theirstructure-to-property relationships, and 3) their poor glass forming ability, whichlimits bulk metallic glasses to sizes on the order of centimeters. We focused onunderstanding the first two major challenges by observing the mechanical propertiesof nanoscale metallic glasses in order to gain insight into its atomic-level structureand deformation mechanisms. We found that anomalous stable plastic flow emergesin room-temperature MGs at the nanoscale in wires as little as ~100 nanometerswide regardless of fabrication route (ion-irradiated or not). To circumvent experimentalchallenges in characterizing the atomic-level structure, extensive moleculardynamics simulations were conducted using approximated (embedded atommethod) potentials to probe the underlying processes that give rise to plasticity innanowires. Simulated results showed that mechanisms of relaxation via the samplefree surfaces contribute to tensile ductility in these nanowires. Continuing with characterizingnanoscale properties, we studied the fracture properties of nano-notchedMGnanowires and the compressive response of MG nanolattices at cryogenic (~130K) temperatures. We learned from these experiments that nanowires are sensitiveto flaws when the (amorphous) microstructure does not contribute stress concentrations,and that nano-architected structures with MG nanoribbons are brittle at lowtemperatures except when elastic shell buckling mechanisms dominate at low ribbonthicknesses (~20 nm), which instead gives rise to fully recoverable nanostructures regardlessof temperature. Finally, motivated by understanding structure-to-propertyrelationships in MGs, we studied the disordered atomic structure using a combinationof in-situ X-ray tomography and X-ray diffraction in a diamond anvil celland molecular dynamics simulations. Synchrotron X-ray experiments showed theprogression of the atomic-level structure (in momentum space) and macroscale volumeunder increasing hydrostatic pressures. Corresponding simulations providedinformation on the real space structure, and we found that the samples displayedfractal scaling (rd ∝ V, d < 3) at short length scales (< ~8 A), and exhibited acrossover to a homogeneous scaling (d = 3) at long length scales. We examinedthis underlying fractal structure of MGs with parallels to percolation clusters anddiscuss the implications of this structural analogy to MG properties and the glasstransition phenomenon." @default.
- W2462677943 created "2016-07-22" @default.
- W2462677943 creator A5087711382 @default.
- W2462677943 date "2016-01-01" @default.
- W2462677943 modified "2023-09-27" @default.
- W2462677943 title "Atomic-Level Structure and Deformation in Metallic Glasses" @default.
- W2462677943 doi "https://doi.org/10.7907/z95q4t2b." @default.
- W2462677943 hasPublicationYear "2016" @default.
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