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- W2463563061 abstract "Because of their chemical stability and relative inertness, lithium-graphite intercalation compounds have garnered considerable interest as a substitute for metallic lithium or lithium alloy-based anodes in rechargeable solid electrolyte batteries. Recently, significantly higher intercalation levels have been reported for disordered and turbostratic carbon materials. We are investigating the effect of the microstructure of these carbon materials on the intercalation process and the local environments and spatial organization of the lithium ions. Our study focuses on the relationship between microstructure and performance of these materials, as addressed by solid state nuclear magnetic resonance (NMR). The aim of this work is to characterize the intercalated materials, to distinguish sites where lithium binds or associates structures which may lead to material failure. We have used {sup 7}Li magic angle spinning NMR to identify lithium sites within the carbon framework and correlate them with performance factors, and double resonance techniques to monitor dipolar interactions between the Li and the framework species (C, N, H)." @default.
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- W2463563061 date "1997-12-31" @default.
- W2463563061 modified "2023-09-26" @default.
- W2463563061 title "NMR investigation of lithium-intercalated carbon materials for battery applications" @default.
- W2463563061 hasPublicationYear "1997" @default.
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