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• W2463705092 startingPage "11660" @default.
• W2463705092 abstract "The kinetic/thermodynamic origin of preferential enrichment (PE), which is a spontaneous enantiomeric resolution phenomenon applicable to racemic crystals, is described. The mechanism of PE, which was unveiled with respect to the first-generation of chiral organic compounds showing PE, has been interpreted in terms of a nonlinear complexity phenomenon including two unique processes: a solvent-assisted solid-to-solid polymorphic transition and subsequent selective redissolution of the excess one enantiomer from the transformed disordered crystals into the mother liquor. The present works confirm that PE takes place because of the unique nonlinear solubility properties of the two enantiomers after the occurrence of a polymorphic transition under PE crystallization conditions at high supersaturation. Furthermore, a ternary phase diagram that is consistent with the mechanism of PE is proposed." @default.
• W2463705092 created "2016-07-22" @default.
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• W2463705092 date "2016-07-13" @default.
• W2463705092 modified "2023-09-27" @default.
• W2463705092 title "A Kinetic/Thermodynamic Origin of Regular Chiral Fluctuation or Symmetry Breaking Unique to Preferential Enrichment" @default.
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• W2463705092 doi "https://doi.org/10.1002/chem.201601550" @default.
• W2463705092 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27406004" @default.
• W2463705092 hasPublicationYear "2016" @default.
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