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• W2464151878 startingPage "9877" @default.
• W2464151878 abstract "The NiAs-type structure is one of the most common structures in solids, but metal order has been almost exclusively limited to chalcogenides. The synthesis of HfMnSb2 is reported with a novel metal-ordered NiAs-type structure. HfMnSb2 undergoes a conical spin order below 270 K, in marked contrast to conventional magnetic order observed in NiAs-type pnictides. We argue that the layered arrangement of Hf and Mn makes it a quasi 2D magnet, where the Mn layers with localized magnetic moments (Mn(2+) ; S=5/2) can interact only through RKKY interactions, instead of metal-metal bonding that is otherwise dominant for typical NiAs-type pnictides. This result suggests that controlling order-disorder in NiAs-type pnictides enables a study of 2D-to-3D crossover behavior in itinerant magnetic system." @default.
• W2464151878 created "2016-07-22" @default.
• W2464151878 creator A5013907244 @default.
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• W2464151878 date "2016-06-29" @default.
• W2464151878 modified "2023-10-16" @default.
• W2464151878 title "HfMnSb ₂ : A Metal‐Ordered NiAs‐type Pnictide with a Conical Spin Order" @default.
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• W2464151878 doi "https://doi.org/10.1002/anie.201602066" @default.
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• W2464151878 hasPublicationYear "2016" @default.
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