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- W2464320106 abstract "Measuring the concentration of the free thiocyanate ion and the nontransformed [Cr(NCS) 4 (benztriazole) 2 ] - ion, the rate constants of the solvolysis process have been calculated. The solvolysis includes two parallel reactions - the substitution of thiocyanate ions and of benztriazole molecules. The first stage of the solvolysis is the substitution of a single SCN - ; this reaction is of first order with regard to the complex ion. This reaction is followed by the very fast substitution of the second SCN - . The parallel benztriazol substitution reaction seems to he a third order one, first order with regard to the complex ion and second order with regard to ethanol. The influence of the acidity has been studied." @default.
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- W2464320106 date "2002-08-31" @default.
- W2464320106 modified "2023-10-18" @default.
- W2464320106 title "Solvolysis of the [Cr(NCS)4(benztriazole)2]- ion in ethanol-water mixtures" @default.
- W2464320106 doi "https://doi.org/10.5281/zenodo.5843274" @default.
- W2464320106 hasPublicationYear "2002" @default.
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