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- W2464755761 abstract "The operating principle of direct alcohol fuel cells is based on the electrochemical oxidation of alcohols such as methanol or ethanol. Palladium nanocrystals are promising catalysts in the electrochemical oxidation of methanol and ethanol in basic media. We demonstrate the alignment of monodisperse palladium nanocrystals into two-dimensional arrays by self-assembly and the subsequent integration as catalysts for the electrochemical oxidation of methanol (MOR) and ethanol (EOR). The nanocrystal arrays exhibit high activity as a consequence of suppressed accumulation into bulk agglomerates, i e. minimized loss of active surface area. The resulting catalytic activity for the MOR and EOR on Pd nanocrystal arrays at the anodic oxidation peak achieve approximately 1040 A g− 1 and 5500 A g− 1, respectively (0.5 M NaOH at a scan rate of 50 mV s− 1 with 1.0 M alcohol concentration)." @default.
- W2464755761 created "2016-07-22" @default.
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- W2464755761 date "2016-09-01" @default.
- W2464755761 modified "2023-10-18" @default.
- W2464755761 title "Electrochemical oxidation of methanol and ethanol on two-dimensional self-assembled palladium nanocrystal arrays" @default.
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- W2464755761 doi "https://doi.org/10.1016/j.tsf.2016.07.013" @default.
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