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- W2464759907 abstract "AbstractUnder hydrothermal conditions, four lanthanide coordination polymers were synthesized based on 4-(4,5-dicarboxy-1H-imidazol-2-yl)pyridine 1-oxide (H3DCImPyO), with the molecular forumulas [Eu(HDCImPyO)·(H2O)2·(CHO2)]n (1), [Sm(HDCImPyO)·(H2O)2·(HCO2)]n (2), {[La(HDCImPyO)·(H2O)·(HCO2)]·O2}n (3) and {[Y(HDCImPyO)·(C2O4)·(H2O)2]·H2O}n (4). With diverse coordination modes, they were further characterized by elemental analysis, infrared spectroscopy, dielectric measurement, and single-crystal X-ray structural analysis. Complexes 1 and 2 were isostructural and had similar structures with {44, 62} topology. Complex 1 exhibited strong fluorescent emission in the solid state at room temperature. In 3, HDCImPyO2− adopted μ4-kO, O′: kO′, O′′: O′′′: O′′′′ coordination to bridge four La(III) ions to form a 3-D framework with {4. 52}2{42. 510. 612. 7. 83} topology. In 4, both HDCImPyO2− ligands and Y3+ cations were simplified as linkers to form an interpenetrating 3-D framework with {413. 62}2{422. 66} topology." @default.
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- W2464759907 date "2016-07-20" @default.
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- W2464759907 title "Synthesis, structures, luminescent and dielectric properties of lanthanide coordination polymers" @default.
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- W2464759907 doi "https://doi.org/10.1080/00958972.2016.1209190" @default.
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