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• W2465184534 startingPage "6352" @default.
• W2465184534 abstract "In small organic molecules with adenine (A) moieties the nucleobases usually form hydrogen-bonded AAA tapes with trans Watson–Crick/Hoogsteen base pairs. In the crystal structure of ethylene-9,9′-diadenine tetra-1,1,1,3,3,3-hexafluoro-2-propanol solvate presented here, the hydroxyl group of the co-crystallized solvent molecules replaces the adenine –NH2 group as donor for the attractive N7 acceptor, leading instead to a highly solvated structure with less common trans Watson–Crick/Watson–Crick base pairs. The properties of hexafluoro-2-propanol as a hydrogen bond pattern modifier was subsequently demonstrated by using it as a crystallization solvent for 9-methyladenine, yielding a structure with the same hydrogen bonds and solvent content as the diadenine analogue." @default.
• W2465184534 created "2016-07-22" @default.
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• W2465184534 date "2016-01-01" @default.
• W2465184534 modified "2023-09-26" @default.
• W2465184534 title "Watson–Crick base pairing in 9-methyladenine and ethylene-9,9′-diadenine structures with close to 70% solvent content" @default.
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• W2465184534 doi "https://doi.org/10.1039/c6ce01159d" @default.
• W2465184534 hasPublicationYear "2016" @default.
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