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- W2465310001 abstract "The structures and powder X-ray reference diffraction patterns of the “natural superlattice” series Bi 1− x Pb x OCuSe ( x = 0, 0.02, 0.04, 0.06, 0.08, and 0.10) have been investigated. As the ionic radius of Pb 2+ is greater than that of Bi 3+ , the unit-cell volume of Bi 1− x Pb x OCuSe increases progressively from x = 0 to 0.1, namely, from 137.868(5) to 139.172(11) Å 3 , as expected. The structure of Bi 1− x Pb x OCuSe is built from [Bi 2(1− x ) Pb 2 x O 2 ] 2(1− x )+ layers normal to the c -axis alternating with [Cu 2 Se 2 ] 2(1− x )− fluorite-like layers. Pb substitution in the Bi site of Bi 1− x Pb x OCuSe leads to the weakening of the “bonding” between the [Bi 2(1− x ) Pb 2 x O 2 ] 2(1− x )+ and the [Cu 2 Se 2 ] 2(1− x )− layers. Powder patterns of Bi 1− x Pb x OCuSe were submitted to be included in the Powder Diffraction File." @default.
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- W2465310001 date "2016-07-04" @default.
- W2465310001 modified "2023-09-22" @default.
- W2465310001 title "X-ray powder diffraction reference patterns for Bi1−xPbxOCuSe" @default.
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- W2465310001 doi "https://doi.org/10.1017/s0885715616000361" @default.
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