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- W2465640623 abstract "A series of ordered mesoporous organic–inorganic hybrid material was designed by using the amine-functionalized SBA-15 (PdX2@SBA-15/NY, Y = 1, 2) as solid support for palladium complexes. Among them, the Pd(OAc)2/ethylenediamine complex encapsulated into SBA-15 (Pd(OAc)2@SBA-15/PrEn or Pd(OAc)2@SBA-15/PrNHEtNH2) exhibits higher activity and selectivity toward Suzuki cross-coupling reaction under aerobic conditions and water solvent mixture. The SBA-15/PrEn supported palladium pre-catalyst could be separated easily from reaction products and used repetitively several times, showing its superiority over homogeneous catalysts for industrial and chemical applications. Copyright © 2013 John Wiley & Sons, Ltd." @default.
- W2465640623 created "2016-07-22" @default.
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- W2465640623 date "2013-04-29" @default.
- W2465640623 modified "2023-09-27" @default.
- W2465640623 title "Pd(OAc)<sub>2</sub> @SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyauracross-coupling reaction in aqueous media" @default.
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- W2465640623 doi "https://doi.org/10.1002/aoc.2986" @default.
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