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- W2465875280 abstract "A novel Schiff-base oxime sensor H2L with the ONON chelating moieties was designed and synthesized based on condensation reaction. Different methods such as elemental analyses, FT-IR, 1H and 13C NMR were fully utilized in characterizing the structure of sensor H2L. The UV–vis spectra of the Zn2+ complex exhibit four clear isosbestic points which may be assigned to the ONON moieties binding to Zn2+. Sensor H2L operates on the CHEF and PET mechanisms, and the tendency of Zn2+ to strongly enhance fluorescence of sensor H2L was explored. Fluorescence measurements show that sensor H2L has excellent fluorescent selectivity for Zn2+ over many other metal ions based on intramolecular charge-transfer, and the results demonstrate that the binding between sensor H2L and Zn2+ is chemically reversible. The crystal structure of the Zn2+ complex has been characterized by X-ray crystallography." @default.
- W2465875280 created "2016-07-22" @default.
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- W2465875280 date "2017-01-01" @default.
- W2465875280 modified "2023-10-18" @default.
- W2465875280 title "A reversible “turn-on” fluorescent sensor for selective detection of Zn2+" @default.
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- W2465875280 doi "https://doi.org/10.1016/j.snb.2016.07.047" @default.
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