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- W2465897706 abstract "The Cover shows a representative idea of methane to syngas conversion. Energy/fuel related industrial catalysis occurs at high to very high temperatures. A fundamental understanding of them might lead to develop better catalysts to work under milder conditions. C−H activation is a perennial issue and a surprise was waiting to explore it on Mn-doped Ce1−xZrxO2 by molecular beam methods. In their Full Paper, A. Dubey et al. describe a key finding of competition and cooperation among the elementary reactions. Though CO, CO2 and H2O formation are oxidation reactions, the former two occur under O2-less conditions. Diffusion of H-atoms is so fast that it simply desorbs as H2 under O2-less, and forms water under O2-rich conditions. A combination of fast oscillation between O2-rich and lean reaction mixtures with low contact time could lead to highly selective syngas at 700-900 K. More information can be found in the Full Paper by A. Dubey et al. on page 2296 in Issue 13, 2016 (DOI: 10.1002/cctc.201600365)." @default.
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- W2465897706 date "2016-07-06" @default.
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- W2465897706 title "Back Cover: C−H Activation of Methane to Syngas on MnxCe1−x−yZryO2: A Molecular Beam Study (ChemCatChem 13/2016)" @default.
- W2465897706 doi "https://doi.org/10.1002/cctc.201600778" @default.
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