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- W2466041298 abstract "Several new anionic actinide dicarbollide complexes have been prepared through metathesis, transmetallation, and chemical and electrochemical reduction. The alkyl, imido, and halide complexes will be discussed. These coordinatively unsaturated complexes are easily prepared yet highly reactive. The dicarbollide ligand has been shown to stabilize actinide oxidation states of (III) and (IV), and most recently the unusual (V). The U(V) complex was shown to be stable by cyclic voltammetery and prepared independently by bulk electrolysis. The NMR X-ray, and other characterization data will be presented and compared to bis(cyclopentadienyl) analogs. In addition to the reactivity of these complexes, the application of these systems to advanced nuclear materials will be discussed." @default.
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- W2466041298 date "1997-12-31" @default.
- W2466041298 modified "2023-09-23" @default.
- W2466041298 title "Actinide dicarbollide complexes" @default.
- W2466041298 hasPublicationYear "1997" @default.
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