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- W2466331446 endingPage "9171" @default.
- W2466331446 startingPage "9166" @default.
- W2466331446 abstract "Deprotonative directed ortho cupration of aromatic/heteroaromatic C–H bond and subsequent oxidation with t-BuOOH furnished functionalized phenols in high yields with high regio- and chemoselectivity. DFT calculations revealed that this hydroxylation reaction proceeds via a copper (I → III → I) redox mechanism. Application of this reaction to aromatic C–H amination using BnONH2 efficiently afforded the corresponding primary anilines. These reactions show broad scope and good functional group compatibility. Catalytic versions of these transformations are also demonstrated." @default.
- W2466331446 created "2016-07-22" @default.
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- W2466331446 date "2016-07-14" @default.
- W2466331446 modified "2023-10-16" @default.
- W2466331446 title "Direct Hydroxylation and Amination of Arenes via Deprotonative Cupration" @default.
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- W2466331446 doi "https://doi.org/10.1021/jacs.6b03855" @default.
- W2466331446 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27348154" @default.
- W2466331446 hasPublicationYear "2016" @default.
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