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• W2466382302 endingPage "4839" @default.
• W2466382302 startingPage "4829" @default.
• W2466382302 abstract "Luminescent materials play an important role in making solid state white light-emitting diodes (w-LEDs) more affordable home lighting applications. To realize the next generation of solid-state w-LEDs with high color-rendering index (CRI), the discovery of broad band and long emission wavelength luminescent materials is an urgent mission. Regarding this, the oxonitridosilicate Y3Si5N9O with a high nitrogen concentration should be a suitable host material to achieve those promising luminescent properties. In this work, a phase-pure Ce3+-doped Y3Si5N9O was successfully synthesized through the carbothermal reduction and nitridation method. Y3Si5N9O:Ce3+ shows an emission maximum at 620 nm and an extremely broad emission band with a full-width at half-maximum (fwhm) of 178 nm. The electronic and crystal structure calculations indicate an indirect band gap of 2.6 eV (experimental value: 4.0 eV), and identify two Ce3+ sites with different local environments that determine the luminescence properties. The orange..." @default.
• W2466382302 created "2016-07-22" @default.
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• W2466382302 date "2016-06-28" @default.
• W2466382302 modified "2023-10-18" @default.
• W2466382302 title "Extra-Broad Band Orange-Emitting Ce³⁺-Doped Y₃Si₅N₉O Phosphor for Solid-State Lighting: Electronic, Crystal Structures and Luminescence Properties" @default.
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• W2466382302 doi "https://doi.org/10.1021/acs.chemmater.6b02109" @default.
• W2466382302 hasPublicationYear "2016" @default.
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