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• W2466574773 endingPage "8367" @default.
• W2466574773 startingPage "8364" @default.
• W2466574773 abstract "Total synthetic approaches of fullerenes are the holy grail for organic chemistry. So far, the main attempts have focused on the synthesis of the buckminsterfullerene C60. In contrast, access to subunits of the homologue C70 remains challenging. Here, we demonstrate an efficient bottom-up strategy toward a novel bowl-shaped polycyclic aromatic hydrocarbons (PAH) C34 with two pentagons. This PAH represents a subunit for C70 and of other higher fullerenes. The bowl-shaped structure was unambiguously determined by X-ray crystallography. A bowl-to-bowl inversion for a C70 fragment in solution was investigated by dynamic NMR analysis, showing a bowl-to-bowl inversion energy (ΔG(⧧)) of 16.7 kcal mol(-1), which is further corroborated by DFT calculations." @default.
• W2466574773 created "2016-07-22" @default.
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• W2466574773 date "2016-07-01" @default.
• W2466574773 modified "2023-10-18" @default.
• W2466574773 title "Fused Dibenzo[<i>a</i>,<i>m</i>]rubicene: A New Bowl-Shaped Subunit of C₇₀ Containing Two Pentagons" @default.
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• W2466574773 doi "https://doi.org/10.1021/jacs.6b04426" @default.
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• W2466574773 hasPublicationYear "2016" @default.
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