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- W2466595364 abstract "Coordination polymers constructed from metal ions and organic ligands have attracted considerable attention owing to their diverse structural topologies and potential applications. Ligands containing carboxylate groups are among the most extensively studied because of their versatile coordination modes. Reactions of benzene-1,4-dicarboxylic acid (H 2 BDC) and pyridine (py) with Zn II or Co II yielded two new coordination polymers, namely, poly[(μ 4 -benzene-1,4-dicarboxylato-κ 4 O : O ′: O ′′: O ′′′)(pyridine-κ N )zinc(II)], [Zn(C 8 H 4 O 2 )(C 5 H 5 N)] n , (I), and catena -poly[aqua(μ 3 -benzene-1,4-dicarboxylato-κ 3 O : O ′: O ′′)bis(pyridine-κ N )cobalt(II)], [Co(C 8 H 4 O 2 )(C 5 H 5 N) 2 (H 2 O)] n , (II). In compound (I), the Zn II cation is five-coordinated by four carboxylate O atoms from four BDC 2− ligands and one pyridine N atom in a distorted square-pyramidal coordination geometry. Four carboxylate groups bridge two Zn II ions to form centrosymmetric paddle-wheel-like Zn 2 (μ 2 -COO) 4 units, which are linked by the benzene rings of the BDC 2− ligands to generate a two-dimensional layered structure. The two-dimensional layer is extended into a three-dimensional supramolecular structure with the help of π–π stacking interactions between the aromatic rings. Compound (II) has a one-dimensional double-chain structure based on Co 2 (μ 2 -COO) 2 units. The Co II cations are bridged by BDC 2− ligands and are octahedrally coordinated by three carboxylate O atoms from three BDC 2− ligands, one water O atom and two pyridine N atoms. Interchain O—H...O hydrogen-bonding interactions link these chains to form a three-dimensional supramolecular architecture." @default.
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- W2466595364 date "2016-01-19" @default.
- W2466595364 modified "2023-09-27" @default.
- W2466595364 title "Two-dimensional Zn<sup>II</sup>and one-dimensional Co<sup>II</sup>coordination polymers based on benzene-1,4-dicarboxylate and pyridine ligands" @default.
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- W2466595364 doi "https://doi.org/10.1107/s2053229616000814" @default.
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