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• W2466730582 abstract "The first intermolecular asymmetric Michael addition of nitrogen-nucleophiles to α,β-unsaturated carboxylic acids was achieved through a new type of arylboronic acid equipped with chiral aminothiourea. The use of BnONH2 as a nucleophile gives a range of enantioenriched β-(benzyloxy)amino acid derivatives in good yields and with high enantioselectivity (up to 90% yield, 97% enantiomeric excess (ee)). The obtained products are efficiently converted to optically active β-amino acid and 1,2-diamine derivatives." @default.
• W2466730582 created "2016-07-22" @default.
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• W2466730582 date "2016-01-01" @default.
• W2466730582 modified "2023-10-16" @default.
• W2466730582 title "Chiral Integrated Catalysts Composed of Bifunctional Thiourea and Arylboronic Acid: Asymmetric Aza-Michael Addition of α,β-Unsaturated Carboxylic Acids" @default.
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• W2466730582 doi "https://doi.org/10.1248/cpb.c15-00983" @default.
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