FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2468010544> ?p ?o ?g. }

• W2468010544 endingPage "5511" @default.
• W2468010544 startingPage "5504" @default.
• W2468010544 abstract "In this study, the electrochemical behavior of free base and zinc meso-substituted porphyrins is examined by cyclic voltammetry (CV) and density functional theory (DFT). The results show that the half-wave oxidation potential splitting of the two oxidation states (ΔE= second E1/2 - first E1/2) of tetraphenylporphyrin (H2TPP) and its zinc complex (ZnTPP) are higher than those of porphyrins and their zinc complexes with meso-substituted five-membered heterocylic rings. The ΔE values follow the trend of TPP > T(3'-thienyl)P > T(3'-furyl)P > T(2'-thienyl)P for both meso-porphyrins and their respective zinc complexes. By employing DFT calculations, we have found that the trend of ΔE values is consistent with that of highest spin density (HSD) distribution and HOMO-LUMO energy gaps of cationic radicals as well as the π-conjugation between central porphyrin and meso-substituted rings. Also, they exhibit the better resonance between the porphyrin ring with meso-substituted rings as moving from porphyrins and their zinc complexes with phenyl rings to five-membered heterocyclic rings. A good agreement between calculated and experimental results indicates that cationic radicals, especially their spin density distribution, do play an important role in half-wave oxidation potential splitting of meso-porphyrins and their zinc complexes." @default.
• W2468010544 created "2016-07-22" @default.
• W2468010544 creator A5000846574 @default.
• W2468010544 creator A5030736261 @default.
• W2468010544 creator A5033114202 @default.
• W2468010544 creator A5034769576 @default.
• W2468010544 creator A5076643047 @default.
• W2468010544 date "2016-07-12" @default.
• W2468010544 modified "2023-10-12" @default.
• W2468010544 title "Electrochemical Behavior of <i>meso</i>-Substituted Porphyrins: The Role of Cation Radicals to the Half-Wave Oxidation Potential Splitting" @default.
• W2468010544 cites W1966606699 @default.
• W2468010544 cites W1983841203 @default.
• W2468010544 cites W1995000974 @default.
• W2468010544 cites W1995030462 @default.
• W2468010544 cites W1996560815 @default.
• W2468010544 cites W2027190895 @default.
• W2468010544 cites W2032587009 @default.
• W2468010544 cites W2045015127 @default.
• W2468010544 cites W2057269314 @default.
• W2468010544 cites W2062482559 @default.
• W2468010544 cites W2072195206 @default.
• W2468010544 cites W2077678053 @default.
• W2468010544 cites W2121843635 @default.
• W2468010544 cites W2143981217 @default.
• W2468010544 cites W2317460023 @default.
• W2468010544 cites W2331939108 @default.
• W2468010544 doi "https://doi.org/10.1021/acs.jpca.6b03538" @default.
• W2468010544 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27379447" @default.
• W2468010544 hasPublicationYear "2016" @default.
• W2468010544 type Work @default.
• W2468010544 sameAs 2468010544 @default.
• W2468010544 citedByCount "19" @default.
• W2468010544 countsByYear W24680105442016 @default.
• W2468010544 countsByYear W24680105442017 @default.
• W2468010544 countsByYear W24680105442018 @default.
• W2468010544 countsByYear W24680105442019 @default.
• W2468010544 countsByYear W24680105442020 @default.
• W2468010544 countsByYear W24680105442021 @default.
• W2468010544 countsByYear W24680105442022 @default.
• W2468010544 countsByYear W24680105442023 @default.
• W2468010544 crossrefType "journal-article" @default.
• W2468010544 hasAuthorship W2468010544A5000846574 @default.
• W2468010544 hasAuthorship W2468010544A5030736261 @default.
• W2468010544 hasAuthorship W2468010544A5033114202 @default.
• W2468010544 hasAuthorship W2468010544A5034769576 @default.
• W2468010544 hasAuthorship W2468010544A5076643047 @default.
• W2468010544 hasConcept C109214941 @default.
• W2468010544 hasConcept C116858620 @default.
• W2468010544 hasConcept C121332964 @default.
• W2468010544 hasConcept C139066938 @default.
• W2468010544 hasConcept C139210041 @default.
• W2468010544 hasConcept C14158195 @default.
• W2468010544 hasConcept C147597530 @default.
• W2468010544 hasConcept C147789679 @default.
• W2468010544 hasConcept C152365726 @default.
• W2468010544 hasConcept C17525397 @default.
• W2468010544 hasConcept C178790620 @default.
• W2468010544 hasConcept C183882617 @default.
• W2468010544 hasConcept C185592680 @default.
• W2468010544 hasConcept C188027245 @default.
• W2468010544 hasConcept C192386470 @default.
• W2468010544 hasConcept C2776371256 @default.
• W2468010544 hasConcept C2777869211 @default.
• W2468010544 hasConcept C2778401137 @default.
• W2468010544 hasConcept C2779480358 @default.
• W2468010544 hasConcept C2780378348 @default.
• W2468010544 hasConcept C32909587 @default.
• W2468010544 hasConcept C52859227 @default.
• W2468010544 hasConcept C535196362 @default.
• W2468010544 hasConcept C75473681 @default.
• W2468010544 hasConceptScore W2468010544C109214941 @default.
• W2468010544 hasConceptScore W2468010544C116858620 @default.
• W2468010544 hasConceptScore W2468010544C121332964 @default.
• W2468010544 hasConceptScore W2468010544C139066938 @default.
• W2468010544 hasConceptScore W2468010544C139210041 @default.
• W2468010544 hasConceptScore W2468010544C14158195 @default.
• W2468010544 hasConceptScore W2468010544C147597530 @default.
• W2468010544 hasConceptScore W2468010544C147789679 @default.
• W2468010544 hasConceptScore W2468010544C152365726 @default.
• W2468010544 hasConceptScore W2468010544C17525397 @default.
• W2468010544 hasConceptScore W2468010544C178790620 @default.
• W2468010544 hasConceptScore W2468010544C183882617 @default.
• W2468010544 hasConceptScore W2468010544C185592680 @default.
• W2468010544 hasConceptScore W2468010544C188027245 @default.
• W2468010544 hasConceptScore W2468010544C192386470 @default.
• W2468010544 hasConceptScore W2468010544C2776371256 @default.
• W2468010544 hasConceptScore W2468010544C2777869211 @default.
• W2468010544 hasConceptScore W2468010544C2778401137 @default.
• W2468010544 hasConceptScore W2468010544C2779480358 @default.
• W2468010544 hasConceptScore W2468010544C2780378348 @default.
• W2468010544 hasConceptScore W2468010544C32909587 @default.
• W2468010544 hasConceptScore W2468010544C52859227 @default.
• W2468010544 hasConceptScore W2468010544C535196362 @default.
• W2468010544 hasConceptScore W2468010544C75473681 @default.
• W2468010544 hasFunder F4320322795 @default.
• W2468010544 hasIssue "28" @default.
• W2468010544 hasLocation W24680105441 @default.
• W2468010544 hasLocation W24680105442 @default.

• next