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• W2469596983 startingPage "1037" @default.
• W2469596983 abstract "The structures of two zinc complexes containing bidentate benzene-1,2-diamine ligands are reported. (Benzene-1,2-diamine-κ 2 N , N ′)dichloroidozinc, [ZnCl 2 (C 6 H 8 N 2 )], (I), displays a distorted tetrahedral coordination sphere for the metal cation. The diamine ligand and the Zn atom reside on a crystallographic mirror plane. In the 1:1 co-crystal salt trans -diaquabis(4,5-dimethylbenzene-1,2-diamine-κ 2 N , N ′)zinc chloride–4,5-dimethylbenzene-1,2-diamine (1/1), [Zn(C 8 H 12 N 2 ) 2 (H 2 O) 2 ]Cl 2 ·2C 8 H 12 N 2 , (II), the zinc(II) complex cation exhibits a tetragonally distorted octahedral coordination sphere. The Zn atom sits on a crystallographically imposed inversion center and the diamine ligands are tilted 30.63 (6)° with respect to the ZnN 4 plane. Both complexes exhibit extensive hydrogen bonding. In (I), a stacked-sheet extended structure parallel to (101) is observed. In (II), the co-crystallized diamine is hydrogen-bonded to the complex cation via O—H...N and N—H...N linkages. These units are in turn linked into planes along (200) by O—H...Cl and N—H...Cl hydrogen bonds." @default.
• W2469596983 created "2016-07-22" @default.
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• W2469596983 date "2016-06-24" @default.
• W2469596983 modified "2023-09-25" @default.
• W2469596983 title "Structural characterization of two benzene-1,2-diamine complexes of zinc chloride: a molecular compound and a co-crystal salt" @default.
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• W2469596983 doi "https://doi.org/10.1107/s2056989016010033" @default.
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