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- W2469958284 abstract "The polyfunctional ligand 2-imidazolidone, HimiO, C 3 H 6 N 2 O, reacts rapidly with cobalt chloride hexahydrate at ambient temperature to produce the deep blue product [Co(HimiO) 6 ][CoCl 4 ], 2, which can be kept in solutionor isolated as stable crystals. A solution of 2 reacts under slightly more forcing conditions with replacement of two HimiO ligands of the cation by water to give the pale pink compound [Co(HimiO)4(H 2 O) 2 ]Cl 2 .2HimiO, 3, which is isolated only in crystalline form. Upon dissolution in acetone, compound 3 reverts to 2. Crystals of 3 display full use of the hydrogen bonding capabilities of the functional groups, both donors and acceptors, and are comprised of unbounded columnar aggregates held together into bundles by hydrogen bonding with interstitial, unligated HimiO molecules. The aqua ligand plays a key hydrogen-bonding role in the formation of both the columns and the bundles. It is concluded that compound 2 is the favored product in solution and that the formation of stable aggregates drives the crystallization of 3, which is favored in the solid state." @default.
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- W2469958284 date "2003-09-01" @default.
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- W2469958284 title "Effect of supramolecular aggregation on coordination in cobalt (II) complexes of 2-imidazolidone" @default.
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