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- W2469968347 abstract "A regioselective synthesis of carbazole analogs belonging to both the categories of natural origin, viz., microorganisms and higher plant source is reported. The synthesis of carbazole derivatives possessing a methylester group at C-1 position has been achieved by Cadogan cyclization of nitro bi-phenyl derivatives, whereas, the carbazole analog possessing a methylester group at C-3 position was synthesized by Buchwald–Hartwig Pd-catalyzed cyclization of amino bi-phenyl derivatives. Suitably substituted bi-phenyl precursors were accessed from norbornyl α-diketones via Grob fragmentation, O-methylation and DBU aromatization reaction sequence. The reported carbazole derivatives possess structural features that are common with many carbazole natural products: mukonine, clausine-L, murrayafoline-A, and their sibling natural products." @default.
- W2469968347 created "2016-07-22" @default.
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- W2469968347 date "2016-08-01" @default.
- W2469968347 modified "2023-10-10" @default.
- W2469968347 title "Synthesis of carbazole analogs via Grob fragmentation of norbornyl α-diketones" @default.
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- W2469968347 doi "https://doi.org/10.1016/j.tetlet.2016.06.080" @default.
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