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- W2470033266 abstract "BiCoPO5 is isostructural with BiNiPO5, a=7.253(1) Å, b=11.294(1) Å, c=5.230(1) Å, β=107.82(1)°, P21/n, z=4, R1 [I>2σ(I)]=0.025, R1 for all reflections=0.030. Co is in a slightly distorted octahedral coordination with Co–O bonds ranging from 2.007(5) to 2.150(5) Å. Bi is in six-fold coordination to oxygen in a distorted octahedral coordination with Bi–O bonds ranging from 2.129(4) to 2.693(5) Å. The lone-pair electrons are 0.39 Å from the Bi nucleus. The PO4 tetrahedron is quite regular with P–O bonds 1.532(5)–1.558(5) Å. Phases in the solid solution series BiNi1−xCoxPO5, 0≤x≤1 are monoclinic. Magnetic susceptibility measurements show that they are all antiferromagnets with TN varying from 20 K for the pure Ni phase to 15 K for pure Co. The materials are semiconductors with Eg=0.38 ev and Eg=0.9 ev for the Ni and Co compounds, respectively. When monoclinic BiCoPO5 is heated past the melting point to 950°C it decomposes and an orthorhombic phase is formed. Single crystal Weissenberg photographs of this new phase yield lattice parameters a=14.688(3) Å, b=11.229(2) Å, c=5.438(1) Å, space group Ibam or Iba2." @default.
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- W2470033266 date "1999-12-01" @default.
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- W2470033266 title "Crystal Structure and Physical Properties of BiCoPO5" @default.
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- W2470033266 doi "https://doi.org/10.1006/jssc.1999.8450" @default.
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