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- W2470389229 abstract "Abstract The synthesis of the first linear coordinated Cu II complex Cu{N(SiMe 3 )Dipp} 2 ( 1 Dipp=C 6 H 5 ‐2,6Pr i 2 ) and its Cu I counterpart [Cu{N(SiMe 3 )Dipp} 2 ] − ( 2 ) is described. The formation of 1 proceeds through a dispersion force‐driven disproportionation, and is the reaction product of a Cu I halide and LiN(SiMe 3 )Dipp in a non‐donor solvent. The synthesis of 2 is accomplished by preventing the disproportionation into 1 by using the complexing agent 15‐crown‐5. EPR spectroscopy of 1 provides the first detailed study of a two‐coordinate transition‐metal complex indicating strong covalency in the Cu−N bonds." @default.
- W2470389229 created "2016-07-22" @default.
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- W2470389229 date "2016-07-15" @default.
- W2470389229 modified "2023-10-11" @default.
- W2470389229 title "Dispersion‐Force‐Assisted Disproportionation: A Stable Two‐Coordinate Copper(II) Complex" @default.
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- W2470389229 doi "https://doi.org/10.1002/anie.201605061" @default.
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