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- W2470464039 endingPage "613" @default.
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- W2470464039 abstract "Electrochemical behavior of Ag, Bi, Cu, Fe, Ni and Sn substrates on zinc deposition was evaluated over battery cycling by cyclic voltammetry and electrochemical impedance spectroscopy. The effect of Bi, Cu, Ni, and Sn substrates on zinc electrodeposition during battery cycling was investigated using scanning electron microscopy and X-ray diffraction. The corrosion behavior of each metal in 9 M KOH and the corrosion rates of zinc plated on each substrate were analyzed by Tafel extrapolation method from the potentiodynamic polarization curves and electrochemical impedance spectroscopy. Although the charge-transfer resistance (Rct) of zinc electrodeposition is lowest on Sn, Sn eventually corrodes on cycling in alkaline media. Use of Ni as a substrate causes zinc to deteriorate on account of rapid hydrogen evolution. Bi and Cu substrates are more suitable for use as current collectors in zinc-anode alkaline rechargeable batteries because of their low corrosion rate and compact zinc deposition over battery cycling." @default.
- W2470464039 created "2016-07-22" @default.
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- W2470464039 date "2016-09-01" @default.
- W2470464039 modified "2023-10-17" @default.
- W2470464039 title "Impact of anode substrates on electrodeposited zinc over cycling in zinc-anode rechargeable alkaline batteries" @default.
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- W2470464039 doi "https://doi.org/10.1016/j.electacta.2016.07.041" @default.
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