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- W2470581008 abstract "The interaction of water soluble polymers with microemulsions and with surfactants will, when the components are sufficiently concentrated, often result in a phase separation or change in the phase boundaries of the mixture as a function of external variables, such as temperature or salinity. In order to arrive at a better understanding of this technologically important phenomenon, a series of experimental studies was carried out using a variety of water soluble polymers in conjunction with model microemulsion systems. The polymers used included polyethylene oxide, polyvinylpyrrolidone, dextran, xanthan, polyacrylamide, and hydrolyzed polyacrylamide. The surfactants used were either nonionic or anionic and included a variety of alkyl ethoxylates such as members of the commercially available Brij and Tween surfactants, and monoethanolamine salts of alkyl arene sulfonates. Measurements of the phase behavior, as a function of temperature and polymer molecular weight, revealed a number of features that were consistent with a coacervation model of compatibility that is qualitatively similar to that known to occur for two incompatible polymers in a common solvent. Measurements of dilute solution viscosities of polymer-microemulsion mixtures also could be adequately described by this approach. These experiments showed, for example, that the weight average molecular weight (as opposed to the number or z-average molecular weight) of the polymer is the dominant variable in the dependence of the cloud point temperature of the microemulsion-polymer" @default.
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- W2470581008 date "1989-12-30" @default.
- W2470581008 modified "2023-09-27" @default.
- W2470581008 title "Interactions of Water-Soluble Polymers with Microemulsions and Surfactants" @default.
- W2470581008 doi "https://doi.org/10.1021/bk-1989-0384.ch020" @default.
- W2470581008 hasPublicationYear "1989" @default.
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