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- W247136294 abstract "The asymmetric binuclear copper(Ⅰ) complex [Cu2(dppm)2(C7H7N)(μ-HCOO)](NO3) (dppm=Ph2PCH2PPh2,C7H7N=4-vinyl-pyridine) has been prepared and characterized by physicochemical and spectroscopic methods.The complex is photoluminescent at room temperature. It crystallizes in triclinic system, space group P-1 with a=1.2719(3)nm, b=1.8637(4) nm, c=1.1656(2)nm, α=97.16(3)°,β=104.94(3)°, γ=89.39(3)°, V=2.648.1(9)nm^3,Dc=1.390g·cm^-3, Z=2, μ=0.974 mm^-1, R=0.0483 for 5716 independently observed reflections with I>2σ(I).The structure consists of [Cu2(dppm)2(C7H7N)(μ-HCOO)]^+ cations and nitrate anions. The copper atoms show different coordination modes: Cu(1) displays a distorted trigonal and Cu(2) a tetrahedred geometry." @default.
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- W247136294 date "2004-01-01" @default.
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- W247136294 title "Synthesis and Characterization of an Unexpected Asymmetric Binuclear Copper（I） Complex Containing 4-Vinyl-pyridine" @default.
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