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• W2471366314 abstract "Radical involved transformations are now considered as extremely important processes in modern organic synthetic chemistry. According to the demand by atom-economic and sustainable chemistry, direct C(sp(3))-H functionalization through radical oxidative coupling represents an appealing strategy for C-C bond formations. However, the selectivity control of reactive radical intermediates is still a great challenge in these transformations. Here we show a selective radical oxidative C(sp(3))-H/C(sp)-H cross-coupling of unactivated alkanes with terminal alkynes by using a combined Cu/Ni/Ag catalytic system. It provides a new way to access substituted alkynes from readily available materials. Preliminary mechanistic studies suggest that this reaction proceeds through a radical process and the C(sp(3))-H bond cleavage is the rate-limiting step. This study may have significant implications for controlling selective C-C bond formation of reactive radical intermediates by using multimetallic catalytic systems." @default.
• W2471366314 created "2016-07-22" @default.
• W2471366314 creator A5006794114 @default.
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• W2471366314 date "2016-06-24" @default.
• W2471366314 modified "2023-10-08" @default.
• W2471366314 title "Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes" @default.
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• W2471366314 doi "https://doi.org/10.1038/ncomms11676" @default.
• W2471366314 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4931026" @default.
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• W2471366314 hasPublicationYear "2016" @default.
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